Cookies on this website

We use cookies to ensure that we give you the best experience on our website. If you click 'Accept all cookies' we'll assume that you are happy to receive all cookies and you won't see this message again. If you click 'Reject all non-essential cookies' only necessary cookies providing core functionality such as security, network management, and accessibility will be enabled. Click 'Find out more' for information on how to change your cookie settings.

The effect of ST-1 coupling on the intensities in the electron spin resonance spectra of spin-polarized radicals is discussed, and demonstrated in spectra with many hyperfine components for the first time. Both hyperfine-dependent and hyperfine-independent contributions to the polarization occur; the latter could easily be mis-assigned to the action of the triplet mechanism. The effects are demonstrated in radicals produced on photolysis of acetone, both in the presence of diethyl phosphite and in propan-2-ol solution at low temperatures. © 1987.

Original publication

DOI

10.1016/0009-2614(87)80309-3

Type

Journal article

Journal

Chemical physics letters

Publication Date

29/05/1987

Volume

137

Pages

86 - 90